I already tried to right click on workspace switcher, but it doesn't show anything.
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You can do that with Compiz. To install, just press Ctrl+Alt+T on your keyboard to open Terminal. When it opens, run the command(s) below:
sudo apt-get install compiz compizconfig-settings-manager compiz-plugins
Once installed, run the program, and navigate to Window Management --> Workspace Naming, and change the names to whatever you want.
Edit
I just installed using the command above on 14.04, and 16.04, and it works.

Mitch
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compiz-plugins
was missing. Now it works! Thanks! – blueFast May 20 '16 at 12:31