Be sure to have a current and valid backup of all your important data before messing aroud with disks
Say the third disk is connected as /dev/sdc, you booted from /dev/sdb(as you said grub is there), but the running OS is on /dev/sda. Then dd would be the simplest way to clone sdb to sdc. sdc should at minimum be equal in size as sdb
First make sure you have the correct devices by issuing mount (should only show partitions on /dev/sda) and sudo fstab -l (if the third disk is new, there should be no partitions on it, or only one FAT or NTFS).
After being very sure (the following will destroy all data on /dev/sdc) you might use different ways:
Use the standard block copy program:
sudo dd if=/dev/sdb of=/dev/sdc bs=1M
This will copy each block from /dev/sdb to /dev/sdc. See man dd for more information. If you want more options, e.g. a progress indicator, install dcfldd (should be in the default repositories), and run
sudo dcfldd if=/dev/sdb of=/dev/sdc bs=1M
which will give you a status report every 256 blocks. Adding the option statusinterval=N will report every N blocks.
After you copied the disk block by block, you will have to adapt the partition table, as this will not reflect the new disk geometry. For that, start gparted, select the new disk, and resize (enlarge) the last partition to use the whole disk, depending on your partition layout.
If you prefer an all-in-one solution, you may install clonezilla from the default repositories. This program is able to make partition/disk images and to clone partitions/images (see Clonezilla. I did not work with that for long time, so I cannot give any advice here.